Use ex officio to describe a position someone automatically gains because of another job or position she already holds. For example, the United States Vice President is the ex officio President of the Senate.
Ex officio is a Latin phrase that can be used as an adjective or an adverb. Its literal meaning is "out of duty," from officium, "duty," and ex, "out of," and it's been used since ancient Roman times, often to describe someone who holds a membership on a board or committee by virtue of being an elected official or holding some office or position.